Picric acid, due to its low pK a value, possesses distinct physicochemical features from all other nitroaromatic derivatives, enabling the design of fluorescent probes for its sensitive and selective detection. The electrostatic interactions between the positive charge on the fluorescent probe, which arises due to protonation or the presence of a quaternary nitrogen, and the picrate anion ...
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Linker hydrolysis vs. capillary-force-driven channel collapse Chem. Commun., 50 ( 64 ) ( 2014 ), pp. 8944 - 8946 CrossRef View Record in Scopus Google Scholar
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A water-stable In-MOF, constructed based on a conformationally-flexible tetraacid linker, i.e., 2,7-bis(3,5-dicarboxyphenyl)-9,9′-diphenyl-9H-fluorene, i.e., H 4 DPF, is shown to exhibit a significantly enhanced solid-state fluorescence quantum yield (ϕ f) of 23% in comparison with that of the linker (ϕ f ca. 4%) as a consequence of rigidification of the latter by metalation.
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